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Synthesis and Crystal Growth of Two Novel Layered Structures, NaKLaNbO 5 and Na 2 K 2 Gd 4 Nb 2 O 13 , in Molten Hydroxide Salts
β Scribed by Liao, Ju-Hsiou; Tsai, Ming-Chuen
- Book ID
- 120450842
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 170 KB
- Volume
- 2
- Category
- Article
- ISSN
- 1528-7483
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The reaction of UO 3 and TeO 3 with a KCl flux at 800 1C for 3 days yields single crystals of K 4 [(UO 2 ) 5 (TeO 3 ) 2 O 5 ]. The structure of the title compound consists of layered, two-dimensional 2 sheets arranged in a stair-like topology separated by potassium cations. Contained within these s
Two new alkali uranyl vanadates, M 6 (UO 2 ) 5 (VO 4 ) 2 O 5 with M β«Ψβ¬ Na, K, have been synthesized by solid state reactions and their structures determined from single-crystal X-ray di4raction data. They crystallize in the monoclinic system with space group P2 1 /c. Unit cell b, c, and parameters