✦ LIBER ✦

Synthesis and cross-coupling reactions of tetraalkylammonium organotrifluoroborate salts

✍ Scribed by Robert A Batey; Tan D Quach

Book ID: 104232028
Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 138 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)01983-9

No coin nor oath required. For personal study only.

✦ Synopsis

Treatment of organoboronic acids with hydrofluoric acid generates an in situ tetracoordinate hydronium organotrifluoroborate species which undergoes counterion exchange with tetra-n-butylammonium hydroxide. The resultant tetraalkylammonium salts are as air and moisture stable as their potassium organotrifluoroborate counterparts with the added advantage of being readily soluble in organic media. They were found to undergo Pd-catalyzed Suzuki-Miyaura cross-couplings with a variety of aryl-and alkenylhalides under mild conditions. Their Pd-catalyzed cross-coupling with acid halides is also possible for the generation of ketones.

📜 SIMILAR VOLUMES

ChemInform Abstract: Synthesis and Cross

ChemInform Abstract: Synthesis and Cross-Coupling Reactions of Tetraalkylammonium Organotrifluoroborate Salts.

✍ Robert A. Batey; Tan D. Quach 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

Ultrasound-Assisted Synthesis of (Z)- an

Ultrasound-Assisted Synthesis of (Z)- and (E)-Stilbenes by Suzuki Cross-Coupling Reactions of Organotellurides with Potassium Organotrifluoroborate Salts.

✍ Rodrigo Cella; Helio A. Stefani 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 23 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Synthesis and Reactivity of Solid-Suppor

Synthesis and Reactivity of Solid-Supported Organotrifluoroborates in Suzuki Cross-Coupling

✍ Colombel, Virginie; Presset, Marc; Oehlrich, Daniel; Rombouts, Frederik; Molande 📂 Article 📅 2012 🏛 American Chemical Society 🌐 English ⚖ 849 KB

Facile Synthesis of Iodonium Salts by Re

Facile Synthesis of Iodonium Salts by Reaction of Organotrifluoroborates with p-Iodotoluene Difluoride.

✍ Masanori Yoshida; Kanako Osafune; Shoji Hara 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 25 KB

ChemInform Abstract: Preparation of 1,3-

ChemInform Abstract: Preparation of 1,3-Dienyl Organotrifluoroborates and Their Diels—Alder/Cross-Coupling Reactions.

✍ Subhasis De; Cynthia Day; Mark E. Welker 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 45 KB 👁 3 views

Synthesis of Monocarbenepalladium(0) Com

Synthesis of Monocarbenepalladium(0) Complexes and Their Catalytic Behavior in Cross-Coupling Reactions of Aryldiazonium Salts

✍ Kumaravel Selvakumar; Alexander Zapf; Anke Spannenberg; Matthias Beller 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 149 KB 👁 1 views

The first monocarbenepalladium(0) complexes with benzoquinone and naphthoquinone as additional ligands have been prepared. As demonstrated by NMR spectroscopy and X-ray analysis, the complexes show a unique coordination mode giving quinone-bridged dimers. The monocarbenepalladium(0) complexes allow