Synthesis and copolymerization of N-tert-butyldimethylsilylacrylamide: A new acrylamide precursor

✍ Scribed by A. Dasgupta

• Book ID: 103075689
• Publisher: Elsevier Science
• Year: 1996
• Tongue: English
• Weight: 375 KB
• Volume: 32
• Category: Article
• ISSN: 0014-3057
• DOI: 10.1016/0014-3057(95)00156-5

✦ Synopsis

N-tert-Butyldimethylsilylacrylamide, a new acrylamide precursor has been synthesized and characterized.

The monomer has been copolymerized with styrene in an organic phase. The copolymers are hydrolyzed to give compositionally homogeneous styrene-acrylamide copolymers. Characterizations of the copolymers have been performed by a combination of FTIR and 'H NMR spectroscopy, elemental analysis and DSC. The reactivity ratios have been determined by the Kelen Tudos method.