𝔖 Bobbio Scriptorium
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SYNTHESIS AND CONFORMATIONAL INVESTIGATIONS OF SULFATED CARBOHYDRATES1

✍ Scribed by Probst, Katrin; Wessel, Hans

Book ID
111899694
Publisher
Taylor and Francis Group
Year
2001
Tongue
English
Weight
188 KB
Volume
20
Category
Article
ISSN
0732-8303

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Diisobutylaluminum hydride is utilized to reduce pentacene-6,13-diones to the corresponding diols, useful precursors to functionalized pentacenes. This pathway is mild and efficient, and produces the cis-diols as major products. Further, we found the cis-diols adopt endo conformation, which cannot f