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Synthesis and Conformation of Optically Active Poly(phenyl isocyanate)s Bearing an (( S )-(α-Methylbenzyl)carbamoyl) Group

✍ Scribed by Maeda, Katsuhiro; Okamoto, Yoshio


Book ID
127134104
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
131 KB
Volume
31
Category
Article
ISSN
0024-9297

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Two types of optically active itaconamates, a-ethyl 3-N-((R)-a'-methylbenzyl)itaconamate (MBEI) and a-N-((R)-a'-methylbenzyl)/3-ethyl itaconamate (EMBI) were synthesized from itaconic anhydride, (R)-amethylbenzylamine and ethanol. Radical polymerizations of MBEI and EMBI were performed in bulk and i