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Synthesis and Complexation Studies of a Tetra(N,N-dimethyl) Aminoethylamidep-tert-butyl Calix[4]arene and Its Tetramethylammonium Derivative

โœ Scribed by J.K. Cherif; M. Mahouachi; R. Abidi; J. Vicens


Publisher
Springer Netherlands
Year
2006
Tongue
English
Weight
357 KB
Volume
55
Category
Article
ISSN
0923-0750

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The hetero-armedp-(tert -butyl)calix[4]arene 1 was synthesized by a stepwise procedure. This ligand presented a very strong complexing behavior towards Cu', giving the chiral complex 2 and parent species when reacted with Cu" salts. High-resolution NMR techniques were employed for the characterizati