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Synthesis and chiroptical properties of some asymmetric planar dienes.

✍ Scribed by Albert W. Burgstahler; Dale L. Boger; Nandkishor C. Naik

Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
28 KB
Volume
32
Category
Article
ISSN
0040-4020

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## Abstract The large molecules **1**–**3** (69, 90, and 102 atoms, respectively), prepared by cyclotrimerization of enantiomerically pure derivatives of (βˆ’)‐bornyl acetate, show intense ECD spectra, high optical rotation (OR) values (200–1300, in absolute value) dominated in sign and order of magn