Synthesis and Chemistry of CF3C6F4OC6F4NH2 (RFNH2) and Pseudohalogen Derivatives; Crystal Structures of RFX (X = COOH, COCl, CN, N3, NCS, NHCOCONHRF)
✍ Scribed by Thomas M. Klapötke; Burkhard Krumm; Peter Mayer; Holger Piotrowski
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- German
- Weight
- 179 KB
- Volume
- 627
- Category
- Article
- ISSN
- 0372-7874
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## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3