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Synthesis and chemistry of an iron(III) tetraphenylporphyrin with a covalently-attached phenolate tail

โœ Scribed by Michael W. Nee; Chongwoo A. Kim; Sandhya Garg; Michael C. Griffith; Laura S. Mizoue; Paul E. Rauch; Wendy J. Dixon

Book ID
104217939
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
263 KB
Volume
29
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

We report the synthesis of a phenolate-tailed iron(II1) tetraphenylporphyrin, 1. The phenolate ligand is covalently-attached to the porphyrin ring and is coordinated to the u-on(II1) center. This phenolate ligand increases the rate of oxygen atom transfer to the metal center.

The use of iron(II1) porphyrins as chemical models of the heme protein cytochrome P-450 has proven very fruitful. Groves and coworkers have studied model systems composed of an

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