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Synthesis and chemiluminescence of 3,3-diisopropyl-4-methoxy-4-(2-naphthyl)-1,2-dioxetanes

โœ Scribed by Masakatsu Matsumoto; Nobuko Watanabe; Hisako Kobayashi; Mitsunori Azami; Hiroshi Ikawa


Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
227 KB
Volume
38
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Six isomeric 3,

were synthesized and their F--induced chemilmninescences were examined in DMSO. Dioxetane 4 b is a new type of ehemilmninescent substrate which affords intense flash light. The other isomeric naphthyldioxetanes (4c -4t3 exhibit ehemiluminescent properties in agreement with the 'odd~even' relationship.


๐Ÿ“œ SIMILAR VOLUMES


ChemInform Abstract: Synthesis and Chemi
โœ M. MATSUMOTO; N. WATANABE; H. KOBAYASHI; M. AZAMI; H. IKAWA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 27 KB ๐Ÿ‘ 1 views

Synthesis and Chemiluminescence of 3,3-Diisopropyl-4-methoxy-4-(2naphthyl)-1,2-dioxetanes. -The F-induced chemiluminescences of the title dioxetanes, e.g. (I), are examined. The dioxetane (Ib) is a new type of substrate which affords intensive flash light. -(MATSUMOTO, M.;

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โœ Sarojini, B. K. ;Narayana, B. ;Yathirajan, H. S. ;Mayekar, Anil N. ;Bolte, Micha ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› International Union of Crystallography ๐ŸŒ English โš– 516 KB

In the title compound, C 21 H 17 Br 3 O 3 , the two aromatic residues are almost coplanar with one another [dihedral angle = 9.92 (6) ]. The two Br atoms at the Csp 3 atoms are in a trans conformation. Related literature For background, see: Yathirajan et al. (2007).