Synthesis and Chemiluminescence of 3,3-Diisopropyl-4-methoxy-4-(2naphthyl)-1,2-dioxetanes. -The F-induced chemiluminescences of the title dioxetanes, e.g. (I), are examined. The dioxetane (Ib) is a new type of substrate which affords intensive flash light. -(MATSUMOTO, M.;
Synthesis and chemiluminescence of 3,3-diisopropyl-4-methoxy-4-(2-naphthyl)-1,2-dioxetanes
โ Scribed by Masakatsu Matsumoto; Nobuko Watanabe; Hisako Kobayashi; Mitsunori Azami; Hiroshi Ikawa
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 227 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Six isomeric 3,
were synthesized and their F--induced chemilmninescences were examined in DMSO. Dioxetane 4 b is a new type of ehemilmninescent substrate which affords intense flash light. The other isomeric naphthyldioxetanes (4c -4t3 exhibit ehemiluminescent properties in agreement with the 'odd~even' relationship.
๐ SIMILAR VOLUMES
In the title compound, C 21 H 17 Br 3 O 3 , the two aromatic residues are almost coplanar with one another [dihedral angle = 9.92 (6) ]. The two Br atoms at the Csp 3 atoms are in a trans conformation. Related literature For background, see: Yathirajan et al. (2007).