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Synthesis and Characterization of (Z)-[N3NFO]+ and (E)-[N3NFO]+

✍ Scribed by William W. Wilson; Ralf Haiges; Jerry A. Boatz; Karl O. Christe

Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 209 KB
Volume: 46
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200700130

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We report the discovery of a new ternary oxynitride, \(\mathrm{Na}_{3} \mathrm{WO}_{3} \mathrm{~N}\). \(\mathrm{Na}_{3} \mathrm{WO}_{3} \mathrm{~N}\) is synthesized by exposing a eutectic melt consisting of \(\frac{1}{2} \mathrm{Na}_{2} \mathrm{O}: 1 \mathrm{Na}_{2} \mathrm{WO}_{4}\) to a flow of am