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Synthesis and Characterization of Vanadium(IV) Complexes with cis -Inositol in Aqueous Solution and in the Solid-State †

✍ Scribed by Morgenstern, Bernd; Kutzky, Barbara; Neis, Christian; Stucky, Stefan; Hegetschweiler, Kaspar; Garribba, Eugenio; Micera, Giovanni

Book ID
121379308
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
359 KB
Volume
46
Category
Article
ISSN
0020-1669

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A new trinuclear oxovanadium(V) complex with the anionic dmpp ligand (Hdmpp = 3-hydroxy-1,2-dimethyl-4-pyridinone), [V 3 O 6 (dmpp) 3 (H 2 O)](H 2 O) 2 , was isolated from the reaction of Hdmpp, KOH and sodium metavanadate at pH 4.5. The solid state structure of the [V 3 O 6 (H 2 O)(dmpp) 3 ](H 2 O)