Synthesis and characterization of unsymmetrically substituted dienophilic nickel phthalocyanines for Diels-Alder reactions
β Scribed by Youssef, Tamer E.; Hanack, Michael
- Book ID
- 120886986
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 472 KB
- Volume
- 06
- Category
- Article
- ISSN
- 1088-4246
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The octasubstituted (phthalocyanine)nickel complexes 4a,b, synthesized using a statistical approach. Their tetracyclone adducts 17, 18a,b,c can be used for the synthesis of ladder-soluble in common organic solvents, bearing four dienophilic functionalities were synthesized from the corresponding typ
Unsymmetric push-pull phthalocyanines with a high degree of conjugation achieved by introducing Ο-delocalized electron substituents were synthesized by statistical condensation of two different diiminoisoindolines. The characterization and spectroscopic properties of these push-pull phthalocyanines