Synthesis and characterization of two ruthenium(II) heteroleptic complexes of annelated derivatives of 2,2′-bipyridine
✍ Scribed by Amouyal, Edmond; Penaud-Berruyer, Florence; Azhari, Driss; Aït-Haddou, Hassan; Fontenas, Christophe; Bejan, Elena; Daran, Jean-Claude; Balavoine, Gilbert G. A.
- Book ID
- 118061683
- Publisher
- Royal Society of Chemistry
- Year
- 1998
- Tongue
- English
- Weight
- 246 KB
- Volume
- 22
- Category
- Article
- ISSN
- 1144-0546
- DOI
- 10.1039/a708740c
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The optical absorption and luminescence spectra, the electrochemical behavior, and the X-ray crystal structure of a series of three heteroleptic Ru(II) complexes in comparison to [Ru(bipy) 3 ] 2 + are reported. The complexes examined are of the type [Ru(bipy) 2 (bipy%)](PF 6 ) 2 with bipy =2,2%-bipy
We have synthesized a new type of tris-2,2'-bipyridine ligand of 7 and 8 do not interact appreciably, as is evident from their with 4,4'-and 6,6'-disubstituted 2,2'-bipyridine (bpy) units. electrochemical and photophysical data. The lifetime of the The terminal 4,4'-disubstituted 2,2'-bipyridine moi