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Synthesis and characterization of two new cyclobutyl and aryl hydroxyethyl methacrylate monomers and their polymers

✍ Scribed by Mehmet Coşkun; Kadir Demirelli; Ibrahim Erol; Misir Ahmetzade

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
170 KB
Volume
35
Category
Article
ISSN
0887-624X

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✦ Synopsis

Two new hydroxyethyl methacrylates having aryl and cyclobutane rings were synthesized by addition to 1-(epoxyethyl)-3-aryl-3-methylcyclobutane to methacrylic acid. The monomers prepared are 2-(3-methyl-3-phenylcyclobutyl)-2-hydroxyethyl methacrylate (PCHEMA) and 2-(3-methyl-3-mesitylcyclobutyl)-2-hydroxyethyl methacrylate (MCHEMA). Both monomers were polymerized at 60ЊC in 1,4-dioxane solution using benzoyl peroxide as initiator. Poly(PCHEMA) and poly(MCHEMA) and their monomers were characterized by FT-IR and 1 H-and 13 C-NMR techniques. Weight average molecular weights of the polymers were determined for poly(PCHEMA) poly(MCHEMA) by gel permation chromatography. Thermal stabilities of the polymers were essentially the same. Glass transition temperatures for poly(PCHEMA) and poly(MCHEMA) were determined as 105 and 137ЊC, respectively. No changes of the polymers by irradiation with UV light at 254 nm were observed.

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