Synthesis and characterization of thorium and uranium tetraphenylimidophosphinate complexes. Crystal and molecular structures of Th(tpip)4, U(tpip)4 and UCl(tpip)3
✍ Scribed by Adelaide Carvalho; Verónica Garcı́a-Montalvo; Ângela Domingos; Raymundo Cea-Olivares; Noémia Marques; António Pires de Matos
- Book ID
- 108427945
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 144 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0277-5387
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Keywords: Uranium(III) and uranium(IV) complexes / Uranium metal / Hydrides / Chlorides / Triflate complexes / X-ray crystal structure Reactions of pure triflic acid (TfOH) with UH 3 at 20 °C and with The yields were in excess of 90%. The crystal structure of [U(OTf) 2 (OPPh 3 ) 4 ][OTf] (3) was de