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Synthesis and Characterization of the New Alkyl Borates [RB(C 6 F 5 ) 3 ] - (R = CH 2 Me, CHMe 2 , CH 2 CMe 3 ): Utilization of [Me 3 CCH 2 B(C 6 F 5 ) 3 ] - as a Weakly Coordinating Counteranion during Zirconocene-Induced Catalysis of Propylene Polymerization

✍ Scribed by Bavarian, Neda; Baird, Michael C.


Book ID
126145120
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
193 KB
Volume
24
Category
Article
ISSN
0276-7333

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Polymerization of propylene with the [Ar
✍ Jizhu Jin; Shingo Tsubaki; Toshiya Uozumi; Tsuneji Sano; Kazuo Soga 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 367 KB 👁 1 views

Polymerization of propylene was conducted at 0 -150°C with the [ArN(CH2)3NAr]TiClz (Ar = 2,6-'Pr2C6H3) complex using a mixture of ~a l k y l a l u m i n i ~ (AIR3, R = methyl, ethyl and isobutyl) and Ph3CB(C&& as cocatalyst. When AlMe3 or AlEt3 was employed, atactic polypropylene (PP) was selectivel