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Synthesis and Characterization of the Heterometallic Aggregate Pb2Al5(μ3-O)(μ4-O)(μ-OiPr)9(OiPr)3(μ-OAc)3

✍ Scribed by Ashutosh Pandey; Vishnu D. Gupta; Heinrich Nöth

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 217 KB
Volume: 1999
Category: Article
ISSN: 1434-1948
DOI: 10.1002/(sici)1099-0682(199908)1999:8<1291::aid-ejic1291>3.0.co;2-l

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✦ Synopsis

A novel heterometallic aggregate Pb 2 Al 5 (µ 3 -O)(µ 4 -O)(µ-example based on lead and aluminum. This compound has been isolated in high yield and examined by 1 H-, 13 C-, and OiPr) 9 (OiPr) 3 (µ-OAc) 3 obtained from the interaction of Pb(OAc) 2 and Al(O-iPr) 3 is the first structurally characterized 27 Al NMR, and in the solid state by X-ray crystallography.

was obtained in a high and reproducible yield, which ex- [a] Department of Chemistry, Faculty of Science, Banaras Hindu University,

the first example of a system containing the same metal Varanasi 221005, India atom in three different coordination environments. Both the

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