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Synthesis and Characterization of Sterically Encumbered β-Ketoiminate Complexes of Iron(ii) and Zinc(ii)

✍ Scribed by Granum, David M.; Riedel, Paul J.; Crawford, Joshua A.; Mahle, Thomas K.; Wyss, Chelsea M.; Begej, Anastasia K.; Arulsamy, Navamoney; Pierce, Brad S.; Mehn, Mark P.


Book ID
111985336
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
559 KB
Volume
40
Category
Article
ISSN
1477-9226

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Both 1 : 1 and 1 : 2 complexes are formed by zinc(II) halides and triarylphosphines unless electronic and/or steric factors intervene. Tri-p-chlorophosphine (a weaker base than PPh 3 ) forms only a 1 : 1 complex, whereas bulky tri-(ortho-substituted phenyl)phosphines do not react. The complexes ZnX