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Synthesis and Characterization of Sr3FeMoO6.88: An Oxygen-Deficient 2D Analogue of the Double Perovskite Sr2FeMoO6.

✍ Scribed by Gabriel M. Veith; Martha Greenblatt; Mark Croft; K. V. Ramanujachary; J. Hattrick-Simpers; Samuel E. Lofland; Israel Nowik


Publisher
John Wiley and Sons
Year
2005
Weight
11 KB
Volume
36
Category
Article
ISSN
0931-7597

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Ba3Te2O6X2 is obtained by reacting TeO2 in a BaX2 flux at 1000 °C under atmospheric conditions. The samples are characterized by powder and single crystal XRD. All four compounds crystallize in the cubic space group Fd3m with Z = 16. The structures consist of a rigid ∞ 3 [M3Te2O6] 2+ framework (M: S