Synthesis and characterization of some mixed alkyl?carbamates of zinc or cadmium: crystal structures of [Zn4Me2(O2CNEt2)6] and [Zn4Me4(O2CNEt2)4]
✍ Scribed by Abrahams, Isaac; Malik, M. Azad; Motevalli, Majid; O'Brien, Paul
- Book ID
- 127271035
- Publisher
- The Royal Society of Chemistry
- Year
- 1995
- Tongue
- English
- Weight
- 450 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1472-7773
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Two new coordination compounds [Zn(AZT) 4 (H 2 O) 2 ](PA) 2 •4H 2 O and [Zn(AZT) 2 (H 2 O) 4 ](HTNR) 2 •4H 2 O have been prepared by using AZT (3-azido-1,2,4-triazole) as ligands, PA -(picrate) or HTNR -(anion formed by the deprotonation of one of the two hydroxyl-groups of 2,4,6-trinitroresorcinol)
Novel tetrameric rhenium(V) complexes have been prepared from [ReNCl 2 (PPh 3 ) 2 ] and [ReN(PMe 2 Ph) (S 2 CNEt) 2 ], respectively. [ReNCl 2 (PPh 3 ) 2 ] reacts with 1.5 equivalents of KS 2 CNEt 2 in methanol to yield the unusual dark red species [{cyclo-ReN} 4 (S 2 CNEt 2 . The crystal structure