## Abstract Synthesis of (3′__R__) 2‐acetamido‐4‐__N__‐acetyl‐3′‐spiro‐[1,2′:5′,6′‐di‐__O__‐isopropylidene‐α‐D‐glucofuranosyl]‐1,3,4‐thiadiazoline diastereomerically pure is described. We report the physical and spectroscopic characterization of the new heterocyclic compound as well as its immediat
Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone — part II
✍ Scribed by M. A. Martins Alho; N. B. D'Accorso
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 2000
- Tongue
- English
- Weight
- 254 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0022-152X
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The syntheses of 2,3‐dihydro‐1,3,4‐thiadiazoles and 1,3,4‐thiadiazoles from 1,2‐O‐isopropylidene‐α‐D‐xylo‐1,5‐pentadialdo‐1,4‐furanose thiosemicarbazone are described. The new compounds as well as the intermediate products are physically and spectroscopically characterized. We discuss a possible mechanistic pathway for heterocyclization in this particular substrate, using computational calculation.
📜 SIMILAR VOLUMES
## Abstract We report the synthesis of 2,3‐dihydro‐1,3,4‐thiadiazoles and 1,3,4‐thiadiazoles from 1,2:3,4‐di‐__O__‐iso‐propylidene‐α‐D‐galacto‐1,6‐hexodialdo‐1,5‐pyranose thiosemicarbazone. The physical and spectro‐scopic characterizations of the heterocyclic derivatives as well as the intermediate
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v