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Synthesis and characterization of some bis(cyclopentadienyl)titanium(IV) complexes with internally functionalized oximes(LH): sol–gel transformations of Cp2TiCl2, Cp2TiClL and Cp2TiL2 to nano-sized anatase titania

✍ Scribed by Archana Chaudhary; Namita Sharma; Veena Dhayal; Arpita Saxena; Meena Nagar; Rakesh Bohra


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
314 KB
Volume
25
Category
Article
ISSN
0268-2605

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✦ Synopsis


2 ] yielded titania a-c, respectively, at low sintering temperature (600 • C). The powder XRD patterns, IR as well as Raman spectra of all these oxides indicate the formation of nano-sized anatase phase. The SEM images of titania a-c indicate agglomers like surface morphologies. The absorption spectra of a-c exhibit an energy band gap in the range of 3.47-3.71 eV.