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Synthesis and characterization of silver(I) complexes with N-thiophosphorylated thiobenzamide or thiourea and phosphines

✍ Scribed by Maria G. Babashkina; Damir A. Safin; Axel Klein


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
183 KB
Volume
21
Category
Article
ISSN
1042-7163

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✦ Synopsis


A reaction of the potassium salts of RC(S)NHP(S)(OiPr) 2 (R = PhNH, HL I ; Ph, HL II ) with a mixture of AgNO


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## Abstract Silver(I) (**3**) and palladium(II) (**4**) complexes of 1,2‐bis[(anthracen‐9‐ylmethyl)amino]ethane have been synthesized and structurally characterized. X‐ray crystal structure analysis reveals that compound **3** exists as a dinuclear tris(ligand) complex with formula [Ag~2~(**2**)~3~