A four-step synthetic strategy was applied to achieve novel methacrylic monomers. 5-Norbornene-2,2-dimethanol was prepared from a Diels-Alder reaction of cyclopentadiene and acrolein, followed by the treatment of the adduct with an HCHO/ KOH/MeOH solution. The resulting 1,3-diol (1) was then acetali
Synthesis and characterization of side-chain poly(methacrylate)s bearing new azo-moieties
β Scribed by Florica Adriana Nicolescu; Valentin Victor Jerca; Dumitru Mircea Vuluga; Dan Sorin Vasilescu
- Publisher
- Springer
- Year
- 2010
- Tongue
- English
- Weight
- 363 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0170-0839
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The synthesis of two novel optically active monomers containing 9-phenylcarbazole moieties, such as -MCPP], is described. Each monomer has been radically homopolymerized to afford the corresponding optically active polymeric derivatives, which have been fully characterized. Their spectroscopic, the
## Abstract The synthesis of a novel optically active methacrylic monomer containing in the side chain the (__S__)β3βhydroxyβ__N__βphenyl pyrrolidine ring linked to a 4βcyanophenylazocarbazole moiety [(__S__)β**MCAPP**β**C**] and of the analogous achiral monomer (**MCAPEβC**) is described. Both the