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Synthesis and Characterization of Ruthenium(II) Complexes Containing Chiral Bis(ferrocenyl)−P3 or −P2S Ligands. Asymmetric Transfer Hydrogenation of Acetophenone

✍ Scribed by Barbaro, Pierluigi; Bianchini, Claudio; Togni, Antonio


Book ID
111969396
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
306 KB
Volume
16
Category
Article
ISSN
0276-7333

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Chiral Complexes of RhI Containing Binap
✍ Serafino Gladiali; Fabrizia Grepioni; Serenella Medici; Antonio Zucca; Zoltán Be 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 137 KB 👁 1 views

## Abstract The enantiopure complexes **3a** and **3b** [Rh(NBD)(P,S)]^+^BF~4~^−^ [P,S = (__S__)‐2‐(diphenylphosphanyl)‐2′‐(methylthio)‐1,1′‐binaphthalene (**a**); (__S__)‐2‐(diphenylphosphanyl)‐2′‐(isopropylthio)‐1,1′‐binaphthalene (**b**)] have been prepared from [Rh(NBD)(THF)~2~]^+^BF~4~^−^ by r