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Synthesis and characterization of ruthenium dithiocarbamate complexes

✍ Scribed by Carlo Preti; Giuseppe Tosi; Paolo Zannini

Book ID
115975819
Publisher
Elsevier Science
Year
1979
Weight
410 KB
Volume
41
Category
Article
ISSN
0022-1902

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Syntheses of a unique molecule, nickel(ii) dithiocarbamate bearing two ferrocenyl groups (3), and its oxidized product, nickel(iv) dithiocarbamate bearing three ferrocenyl groups (4 ), are reported. Spectroelectrochemical investigations have shown that the complex 4 undergoes a three-electron oxidat