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Synthesis and characterization of rhodium(III), iridium(III), ruthenium(III) and osmium(III) complexes containing sterically hindered heterocyclic ligands

✍ Scribed by Carlo Preti; Giuseppe Tosi


Publisher
Springer
Year
1978
Tongue
English
Weight
785 KB
Volume
3
Category
Article
ISSN
0340-4285

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## Abstract Heating [Rh(dtbpy)(κ~2~‐__C,C′__‐CH~2~CMe~2~C~6~H~4~)(CH~2~CMe~2~Ph)] (1; dtbpy = 4,4′‐di‐__tert__‐butyl‐2,2′‐bipyridyl) in __p__‐xylene at 110 °C resulted in the formation of the 2‐__tert__‐butylphenyl complex [Rh(dtbpy)(κ~2~‐__C,C′__‐CH~2~CMe~2~C~6~H~4~)(C~6~H~4~__t__Bu‐2)] (3). Treat