Synthesis and Characterization of Poly(ϵ-CL)-block-poly(MMA-co-St)-block-poly(ϵ-CL) by Combination of Coordination and Controlled Radical Polymerization
✍ Scribed by Zhenrong Guo; Decheng Wan; Junliang Huang
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 146 KB
- Volume
- 22
- Category
- Article
- ISSN
- 1022-1336
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract A novel block copolymer, poly(ε‐caprolactone)‐__b__‐poly(4‐vinyl pyridine), was synthesized with a bifunctional initiator strategy. Poly(ε‐caprolactone) prepolymer with a 2,2,6,6‐tetramethylpiperidinyloxy (TEMPO) end group (PCL~T~) was first obtained by coordination polymerization, whic
## Abstract The kinetics and controllability of the Ti[OCH~2~CCl~3~]~4~‐initiated atom transfer radical polymerization (ATRP) of __n__‐butyl acrylate were investigated. Then, with Ti[OCH~2~CCl~3~]~4~ as the initiator, poly(ϵ‐caprolactone)‐__block__‐poly(__n__‐butyl acrylate) (PCL‐__b__‐PBA) copolym
## Abstract A series of poly(ϵ‐caprolactone)‐__b__‐poly(ethylene glycol) (PCL‐__b__‐PEG) block copolymers with different molecular weights were synthesized with a salicylaldimine‐aluminum complex in the presence of monomethoxy poly(ethylene glycol). The block copolymers were characterized by ^1^H N