This article deals with the synthesis and structure of poly(vinyl chloride) (PVC) by radical and other polymerization mechanisms. The features of solution, bulk, suspension, and emulsion polymerization of VC are described. Terminal structure and defect structures introduced in the chain during the p
Synthesis and characterization of poly(vinyl chloride)-containing amino groups
✍ Scribed by Helmut Reinecke; Carmen Mijangos
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 315 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0032-3861
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✦ Synopsis
The synthesis of poly(vinyl chloride) (PVC) modified with p-aminothiophenol is described. The presence of free amino groups in the products is proven and their content measured by nuclear magnetic resonance and infrared spectroscopy, and elemental analysis. Modification degrees of up to 30% can be achieved without degradation or other side-reactions. The amino group containing polymers can be easily cross-linked or modified, yielding gels, networks or PVC with covalently bound plasticizers.
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