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Synthesis and characterization of poly(vinyl carbazole) complexes with copper(II) chloride in THF solution

✍ Scribed by Issa A. Katime; Jose R. Ochoa; Carlos Sieiro Del Nido


Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
340 KB
Volume
34
Category
Article
ISSN
0021-8995

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✦ Synopsis


Several polymer-metal complexes were prepared by reacting poly(viny1 carbazole) (PNVC) with copper(I1) chloride, CuC1,.2H,O, in refluxing tetrahydrofurane (THF) for mole ratios of CuC1,.2H2O to monomeric unit (Cu:PNVC ratio) ranging between 0.086 and 4.98. Complexes were characterized by infrared (IR) and elemental analysis. Thermal behavior of complexes was studied by differential thermal analysis (DTA). It appears that THF behaves as a specific solvent for complexation of PNVC with copper(I1) chloride.


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