## Abstract Multiblock copolymers were synthesized through condensation reactions of end‐groups of α,ω‐dichloro‐poly(methylphenylsilylene) with hydroxyl end‐groups of poly(ethylene glycol) or the chain‐ends of ‘living’ polyisoprenyl disodium. Optimum conditions have been sought through kinetic stud
Synthesis and characterization of polystyrene-block-poly(methylphenylsilylene) and polyisoprene-block-poly(methylphenylsilylene)
✍ Scribed by Eric Fossum; Jonathan A. Love; Krzysztof Matyjaszewski
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 636 KB
- Volume
- 499
- Category
- Article
- ISSN
- 0022-328X
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Block copolymers of poly(methylphenylsilylene) and poly(methyl methacrylate) have been synthesized by condensation of a,u-dichloropoly-(methylphenylsilylene) with poly(methyl methacrylate)-lithium. The a,u-dichloropoly(methylphenylsilylene) was synthesized by the Wurtz-type reductive coupling of dic
A poly(p-methylstyrene)-block-polyisoprene-block-poly(p-methyl styrene) thermoplastic elastomer was synthesized via anionic polymerization using n-butyllithium as an initiator. The sequential method used for the synthesis has resulted in a nearly monodispersed polymer with a polydispersity of 1.02.