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Synthesis and characterization of poly[1,5-(3,7-di-tert-butyl)naphthyleneethynylene] by alkyne metathesis

โœ Scribed by Neil Gregory Pschirer; Alan R. Marshall; Chris Stanley; Haskell W. Beckham; Uwe H. F. Bunz


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
44 KB
Volume
21
Category
Article
ISSN
1022-1336

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A photochemical precursor to a pendant conjugated polyradical has been synthesized, poly [3,5-di-tert-butyl-4-[(2,4,6-tri-tert-butylphenyl)oxalato]phenylacetylene], 3. Irradiation of 3 at 77 K in the solid state at รต 300 nm yielded poly(3-5-ditert-butyl-2-oxyphenyl acetylene), 2, with 30-40% of the