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Synthesis and Characterization of Platinum(II)−Bis(boryl) Catalyst Precursors for Diboration of Alkynes and Diynes: Molecular Structures of cis -[(PPh 3 ) 2 Pt(B-4-Bu t cat) 2 ], cis -[(PPh 3 ) 2 Pt(Bcat) 2 ], cis -[(dppe)Pt(Bcat) 2 ], cis -[(dppb)Pt(Bcat) 2 ], ( E )-(4-MeOC 6 H 4 )C(Bcat)CH(Bcat), ( Z )-(C 6 H 5 )C(Bcat)C(C 6 H 5 )(Bcat), and ( Z , Z )-(4-MeOC 6 H 4 )C(Bcat)C(Bcat)C(Bcat)C(4-MeOC 6 H 4 )(Bcat) (cat = 1,2-O 2 C 6 H 4 ; dppe = Ph 2 PCH 2 CH 2 PPh 2 ; dppb = Ph 2 P(CH 2 ) 4 PPh 2 )

✍ Scribed by Lesley, Gerry; Nguyen, Paul; Taylor, Nicholas J.; Marder, Todd B.; Scott, Andrew J.; Clegg, William; Norman, Nicholas C.


Book ID
126029141
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
840 KB
Volume
15
Category
Article
ISSN
0276-7333

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