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Synthesis and characterization of platinum(II) and palladium(II) complexes with 2,5-dimethyl-4-hydroxypyrimidine

✍ Scribed by A. Adeyemo; R.P. Raval

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
393 KB
Volume
131
Category
Article
ISSN
0020-1693

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✦ Synopsis

The binding of Pt(II) and Pd(II) ions to 4-amino-2,5-dimethyl pyrimidine (ADMPY) has been compared with the binding of these same metal ions to 2,.5-dimethyl4-hydroxy pyrimidine (HDMPY), analogue of ADMPY in which the amino group has been replaced by a hydroxyl group. A brief comparison is made with the corresponding Pt(I1) and Pd(I1) complexes of thiamine and oxythiamine.

In this paper we report the synthesis, elemental analyses, infrared spectral data, proton and carbon-13 nuclear magnetic resonance studies of these new complexes.

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## Abstract The synthesis and antimicrobial activity of palladium(II) and platinum(II) complexes derived from heterocyclic bidentate ligands, namely 2‐(2′‐aminophenyl)benzoxazole [L^1^H~2~], 2‐(2′‐hydroxyphenyl)benzoxazole [L^2^H], and 2‐(2′‐mercaptophenyl)benzoxazole [L^3^H], are reported here. Th