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Synthesis and Characterization of Planar-Chiral Cyclopentadienyliron Complexes ( S )- and ( R )-{η 5 -[1-Ph 2 (OH)C-2-Me-4-PhC 5 H 2 ]}Fe(CO) 2 R (R = C⋮CPh, Me, SO 2 Me)

✍ Scribed by Katayama, Taku; Morimoto, Yasushi; Yuge, Michiru; Uno, Mitsunari; Takahashi, Shigetoshi


Book ID
120361661
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
251 KB
Volume
18
Category
Article
ISSN
0276-7333

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✍ Wolfgang Malisch; Marco Hofmann; Martin Nieger; Wolfgang W. Schöller; Andreas Su 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 264 KB 👁 3 views

The novel (ferriomethyl)-substituted silanols C 5 R 5 (OC) 2 Fe-CH 2 -SiMe(RЈ)OH [R = H, RЈ = Me (4a), Ph (4b); R = Me, RЈ = Me (4c)] are obtained by hydrolysis of the chloro(ferriomethyl)silanes C 5 R 5 (OC) 2 Fe-CH 2 -SiMe(RЈ)Cl [R = H, RЈ = Me (3a), Ph (3b); R = Me, RЈ = Me (3c)] in the presence