Synthesis and characterization of Pb(Mg, Mn, Nb)O3
β Scribed by J. Modlich; O. Jarchow; T. Rentschler; A. Relier; U. Bismayer
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 398 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0167-2738
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β¦ Synopsis
Synthesis and structural features of the relaxor ferroelectric PbMg , ,zNb,,,O,, the structural analogue PbMn,,,Nb,,,O, as well as the related phase PbMg, ,4Mn , ,,Nb,,,O, are described. It is shown that pure phases are only obtained when accurate experimental conditions and appropriate precursors are used. The magnetic and dielectric properties are characterized.
Investigations on the thermochemical reactivity of these phases reveal that metal selective reduction/ reoxidation processes, as well as phase segregations, take place.
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The role of the La-addition on the A-site of the perovskite Pb(Mg 1/3 Nb 2/3 )O 3 (PMN) on the phase formation, microstructure and dielectric properties was investigated. Ceramic samples were obtained from PMN and (Pb 1-x La x )(Mg 1+x/3 Nb 2-x/3 )O 3 (PLMN) nanopowders synthesized by the columbite
Nanocrystalline Ba(Mg 1/3 Nb 2/3 )O 3 (BMN) powders were successfully synthesized through a modified combustion synthesis method by using Ba(NO 3 ) 2 , Mg(NO 3 ) 3 β’6H 2 O and Nb 2 O 5 as starting materials. Gel precursor and calcined powders were characterized by thermogravimetric (TG), differentia