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Synthesis and characterization of oxa and thia metallocanes substituted with phosphorodithioate ligands and crystal and molecular structure of 1,3,6-trithia-2-arsocane dimethylphosphorodithioate

✍ Scribed by Miguel-Angel Muñoz-Hernández; Raymundo Cea-Olivares; Simón Hernández-Ortega


Book ID
108328375
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
513 KB
Volume
253
Category
Article
ISSN
0020-1693

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The title compounds were obtained by the reaction of I -aryl-3-trimethylsilyl-l,3-diaza-2-thiaallenes with dichloromonosulfane or 1 -aryl-4-(1 -phtalimidyl)-l,3diaza-2,4-dithia-l,2-butadienes in the presence ofCsF. The latter route also afforded nonsyinmetric derivatives. In contrast, the reaction o