✦ LIBER ✦

Synthesis and characterization of optically active polyamides derived from carbohydrate-based monomers

✍ Scribed by Manuel Bueno; Francisca Zamora; Inmaculada Molina; Hernán A. Orgueira; Oscar Varela; Juan A. Galbis

Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 247 KB
Volume: 35
Category: Article
ISSN: 0887-624X
DOI: 10.1002/(sici)1099-0518(199712)35:17<3645::aid-pola4>3.0.co;2-r

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✦ Synopsis

The synthesis of three new stereoregular AB-type polyamides based on Dribono-1,4-lactone, L-arabinose, and D-xylose has been carried out by the active ester polycondensation method. These polyamides were characterized by elemental analysis, IR and NMR spectroscopies, and powder X-ray diffraction. They displayed optical activity and had a pronounced affinity to water, although they were not soluble in this solvent. The polyamide obtained from D-ribono-1,4-lactone was highly crystalline and yielded films with spherulitic texture.

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