## Abstract **Summary:** A novel copolymer containing perylene bisimide and porphyrin units was synthesized through a Wittigβtype coupling reaction and characterized. An electrochemical experiment showed its electronic properties. Optoelectronic measurements showed a steady and rapid cathodic photo
Synthesis and Characterization of New Types of Perylene Bisimide-Containing Conjugated Copolymers
β Scribed by Xiaorong He; Huibiao Liu; Ning Wang; Xicheng Ai; Shu Wang; Yuliang Li; Changshui Huang; Shuang Cui; Yongjun Li; Daoben Zhu
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 206 KB
- Volume
- 26
- Category
- Article
- ISSN
- 1022-1336
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β¦ Synopsis
Abstract
Summary: Two new poly(perylene bisimide) polymers that contain biphenyl (PPery) and anthracene (PPeAn) groups at the bay position of perylene bisimide are designed and synthesized. The images of scanning and transmission electron microscopies for PPery and PPeAn show that both polymers form uniform nanoparticles. These copolymers emit red photoluminescence at around 640 nm with a relatively high photoluminescence quantum yield, 48% (in solution) for PPery and 68% (in solution) for PPeAn.
Structures of the new copolymers synthesized here: PPery and PPeAn.
imageStructures of the new copolymers synthesized here: PPery and PPeAn.
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