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Synthesis and characterization of new soluble aromatic polyamides based on 4-(1-adamantyl)-1, 3-bis(4-aminophenoxy)benzene

✍ Scribed by Jorge F. Espeso; José G. De La Campa; Angel E. Lozano; Javier De Abajo

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
178 KB
Volume
38
Category
Article
ISSN
0887-624X

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✦ Synopsis

A set of new aromatic polyamides were synthesized by the direct phosphorylation condensation of 4-(1-adamantyl)-1,3-bis-(4-aminophenoxy)benzene with various diacids. The polymers were produced with high yields and moderate to high inherent viscosities (0.43-1.03 dL/g), and the weight-average molecular weights and numberaverage molecular weights, determined by gel permeation chromatography, were in the range of 37,000 -93,000 and 12,000 -59,000, respectively. The polyamides were essentially amorphous and soluble in a variety of solvents such as N,N-dimethylacetamide (DMAc), cyclohexanone, and tetrahydrofuran. They showed glass-transition temperatures in the range of 240 -300 °C (differential scanning calorimetry) and 10% weightloss temperatures over 450 °C, as revealed by thermogravimetric analysis in nitrogen. All the polymers gave strong films via casting from DMAc solutions, and these films exhibited good mechanical properties, with tensile strengths in the range of 77-92 MPa and tensile moduli between 1.5 and 2.5 GPa.

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