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Synthesis and Characterization of New N -(Diphenylphosphino)-Naphthylamine Chalcogenides: X-Ray Structures of (1-NHC 10 H 7 )P(Se)Ph 2 and Ph 2 P(S)OP(S)Ph 2

✍ Scribed by Tomah Al-Masri, Harbi; Emwas, Abdul-Hamid M.; Al-Talla, Zeyad A.; Alkordi, Mohamed H.


Book ID
111895290
Publisher
Taylor and Francis Group
Year
2012
Tongue
English
Weight
274 KB
Volume
187
Category
Article
ISSN
1042-6507

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The ligands [Ph 2 (S)PNHP(X)Ph 2 ] -(X = O, Se) react with InCl 3 coordination geometry in 2 resembles that observed in the three analogous tris-chelates incorporating the corres-in a 3:1 ratio to give a tris-chelate [In{Ph 2 P(O)NP(S)Ph 2 -O,S} 3 ]β€’0.75 C 6 H 6 (2) and the unexpected pentacoordinat