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Synthesis and Characterization of New Cross-like Porphyrin-Naphthalocyanine and Porphyrin-Phthalocyanine Pentads

✍ Scribed by Calvete, Mário J. F.; Tomé, João P. C.; Cavaleiro, José A. S.

Book ID
125433257
Publisher
Journal of Heterocyclic Chemistry
Year
2014
Tongue
English
Weight
508 KB
Volume
51
Category
Article
ISSN
0022-152X

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The antiaromatic macrocycle 2 has been prepared by the reaction of the bipyrrole dialdehyde 1 with hydrazine. In the crystal structure of 2•DMSO molecule 2 is nearly planar, the mean deviation of the 28 atoms of the core from the best least-squares plane being 0.227 Å. AM1 geometric optimization of