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Synthesis and Characterization of New Acrylate and Methacrylate Monomers with Pendant Pyridine Groups

✍ Scribed by Li Cui; Günter Lattermann

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
115 KB
Volume
203
Category
Article
ISSN
1022-1352

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✦ Synopsis

Abstract

To overcome some drawbacks of polyvinylpyridines, new monomers of acrylate and methacrylate type with pendant pyridine groups i.e., 4‐(3‐methacryloylpropyl)pyridine 1a and 4‐(3‐acryloylpropyl)pyridine 1b were successfully prepared, although it turned out to be challenging work to synthesize the acrylate monomer 1b. First polymerization studies showed that the new monomers could be polymerized easily by atom transfer radical polymerization (ATRP). The new polymers show excellent characteristics, such as very good solubility, low glass‐transition temperature, and easy quaternization.
Design and structure of new monomers 1a and 1b.

magnified imageDesign and structure of new monomers 1a and 1b.

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