Synthesis and Characterization of Na5[VO4][O] and Na4[VO4][OH].
β Scribed by Oliver Kerp; Angela Moeller
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 10 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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Single crystals of synthetic Na 3 VB 6 O 13 were obtained by heating a mixture of Na 2 CO 3 .H 2 O, V 2 O 5 , and H 3 BO 3 ; its formula has been determined by the resolution of the structure from X-ray di4raction data. The compound is orthorhombic, space group P2 1 2 1 2 1 ; the unit cell parameter
A new zinc vanadate Zn 2 (OH)VO 4 has been synthesized by an electrochemical-hydrothermal method and characterized by single crystal X-ray diffraction. The compound crystallizes in the orthorhombic system, space group Pnma, a = 14.645(1) A Γ , b = 6.0215(5) A Γ , c = 8.8757(8) A Γ , V = 782.7(1) A Γ
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