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Synthesis and characterization of Mo(nor)4 (nor = 1-norbornyl)

✍ Scribed by Kolodziej, Richard M.; Schrock, Richard R.; Davis, William M.

Book ID
126062634
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
454 KB
Volume
27
Category
Article
ISSN
0020-1669

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Total Synthesis of (+)-Brefeldin C, (+)-
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## Abstract A total synthesis of (+)‐brefeldin C (BFC) and two brefeldin A (BFA) analogues – (+)‐nor‐Me BFA and (+)‐4‐__epi__‐nor‐Me BFA – has been developed. Key features of the syntheses include desymmetrization of __meso__ anhydrides, a Carreira reaction to control the absolute configuration at