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Synthesis and Characterization of Mono-, Bis-, and Tetrakis-Pyridyltriarylporphyrin Pd(II) and Pt(II) Supramolecular Assemblies. Molecular Structure of a Pd-Linked Bisporphyrin Complex 1

✍ Scribed by Yuan, Hongping; Thomas, Leonard; Woo, L. Keith


Book ID
126042198
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
369 KB
Volume
35
Category
Article
ISSN
0020-1669

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Reaction between 2,3,5,6-tetrakis(a-pyridyl)pyrazine (TPP) and the dimer , in which TPP behaves as a bis(bidentate) ligand between the two Pt atoms of the cation. Insertion of SnCl 2 into the Pt-Cl bonds of this compound led to an unusual rearranged product, (2), with a rare example of a pentacoor