✦ LIBER ✦

Synthesis and Characterization of Metal Complexes Derived from Potassium 3-(Benzotriazole-1-carbonylmethyl)-dithiocarbazate

✍ Scribed by Peng-Fei Xu; Zhang-Lu Liu; Shao-Zu Wu

Publisher: Wiley (John Wiley & Sons)
Year: 2010
Weight: 308 KB
Volume: 104
Category: Article
ISSN: 0037-9646
DOI: 10.1002/bscb.19951041002

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✦ Synopsis

The preparation and characterization of some dpositive metal ion complexes derived from potassium 3-(bemotriazdbl-ccrrbylmethyl)-~~iocar~zate (BCDHK) is reported. The d i d m l e x e s of the comporition ML (M = Mn( I[ ), Ni( 1 ), Cu( H ), Cd( H ), Zn( 11 ) andCo( I[ ), n = 0 , l ) andML2 2&0 (M = Pb ( II ) , UO2( VI )) , have been characterized on the basis of elemental analyses R, UV and TGA. IR spectral data indicate that BcDm behaves as either a mononegative or binegative ligand and coordinates in a tridentate or bridging tetradentate manner.

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