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Synthesis and characterization of low- and medium-molecular-weight hyperbranched polyethylenes by chain walking ethylene polymerization with Pd–diimine catalysts

✍ Scribed by Peng Xiang; Zhibin Ye; Ramesh Subramanian


Book ID
113857316
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
993 KB
Volume
52
Category
Article
ISSN
0032-3861

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## Abstract We report herein a quantitative end‐capping chemistry for the efficient synthesis of monotelechelic hyperbranched polyethylenes containing various ω‐end functionalities by quenching Pd‐diimine catalyzed ethylene “living” polymerization with styrene derivatives. This chemistry utilizes t