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Synthesis and characterization of KV3P4O16: A new mixed-valence vanadium(III,IV,IV) disphosphate

✍ Scribed by Chi-Shen Lee; Kwang-Hwa Lii


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
587 KB
Volume
92
Category
Article
ISSN
0022-4596

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The solution-phase synthesis, single crystal structure, and some physical properties of CN 3 H 6 β€’ VO(H 2 O)(HPO 4 ) (H 2 PO 4 ) β€’ H 2 O, a new guanidinium vanadium (IV) hydrogen phosphate hydrate, are reported. This phase is built up from one-dimensional chains of VO 5 (H 2 O) octahedra and (H 2 /H